Chemical precipitation and their color table. Color chemistry of qualitative reactions. Motivation for learning activities

Colored rains are often frightening by their appearance: while water of an amazing color is poured onto the ground, people usually begin to feverishly immediately remember whether there have recently been any chemical emissions from an industrial enterprise located nearby (it becomes especially scary if you are on outside when the black rain was pouring). In fact, red, white, yellow, green rain is not always associated with anthropogenic human activities and often has a natural character.

Colored rains consist of the most common water droplets, which, before spilling onto the ground, mixed with natural impurities. These can be leaves, flowers, small grains or sand brought into the upper layers of the atmosphere by a strong wind or tornado, which gave the drops an interesting and unusual shade, for example, chalk particles create white rain.

Black, chocolate, red, green, yellow and white rain can fall everywhere - both on the European continent and elsewhere in the world. People have known about strange colored rains for a long time, Plutarch and Homer recalled them in their writings. You can also often find their description in Medieval literature.

Rain with a red tint

Precipitation can be of different shades, but red rains make a particularly shocking impression on people. Showers of this particular color have long been considered an unkind sign and a herald of the approaching war. Both ordinary people and eminent philosophers of antiquity have always been wary of such precipitation. For example, Plutarch, when he wrote about the red rain that fell on earth surface after battles with Germanic tribes, he argued that the raindrops acquired their hue precisely because of the bloody fumes from the battlefield. According to him, it was they who saturated the air and gave the water droplets a brown tone.

It is interesting that it is red rain that falls on the earth's surface most often (usually either in Europe or near the African continent). Why exactly this happens - for modern scientists has long been no mystery, and they do not see any mysticism in this phenomenon.

The cause of the red rain is the ordinary dust of the African desert (it is also called trade wind dust), which contains a huge number of red microorganisms:

A strong wind or tornado raises dust with red particles into the upper atmosphere, from where air currents carry it to the European continent.
Over the European continent, dust mixes with water droplets and colors them.
After that, drops in the form of rain fall down, surprising and amazing the local population.

This is far from the only explanation for this phenomenon. For example, several years ago in India for two months it was raining red (which could not but alarm the local population) - and the African dust had nothing to do with it. Since during this period, both the weather and the wind changed their direction several times, while the showers almost did not stop.

Red rain also negatively affected the leaves, they quickly became uneasy dry, but they also acquired a dirty gray tint, after which they fell off - a phenomenon not typical for India at this time of year.

Scientists have put forward a variety of reasons for this phenomenon. There were suggestions that the impurities that paint the rain red are of extraterrestrial origin and are associated with an exploded meteorite in the upper atmosphere, the microparticles of which mixed with the precipitation. Another version, which was adhered to by more skeptical scientists, and along with them the Indian government, said that the color of precipitation was quite strongly influenced by the spores growing on trees of algae from the lichen family, therefore, the red color of rain is absolutely harmless to living organisms.

Black rain

Black rain falls much less frequently than red rain. It appears due to the mixing of water droplets with volcanic or cosmic (meteorite explosion) dust. Black rain is often dangerous - if it is caused by industrial enterprises, whose activities are associated, for example, with the combustion of coal or the processing of petroleum products.

For example, in the late 90s, during the hostilities in Yugoslavia, several petrochemical enterprises were destroyed, after which a black rain fell, containing a lot of heavy metals and organic compounds harmful to human health and life. Black rain also had a negative impact on the environment, as the soil, groundwater and one of the most big rivers Europe - Danube.

Snow white rain

For regions with chalky rocks, milky rain (white rain) is a fairly frequent phenomenon, since raindrops here often contain the smallest particles of chalk and white clay. At the same time, white rain may well fall in other places of our planet.

For example, in the capital of a European city several years ago there was a milky rain, after which uneasy white puddles appeared on the roads, and with a lot of foam, which extremely frightened the locals.

Experts have not been able to fully determine what exactly caused the appearance of such a phenomenon. Some agreed that the white rain fell due to the active construction of houses and roads, which was taking place in the city during this period. Others have suggested that the milky rain was caused by spores of blooming ragweed, which were just flying in the air.

All experts unambiguously agreed that white rain is dangerous to the health of local residents, especially allergy sufferers, asthmatics, as well as people with diseases of the lungs and bronchi.

Yellow and green precipitation

You can get under green or yellow rain when the pollen of various plants (both flowers and trees) is mixed with water drops. For example, when mixed with birch particles, green rain often falls. But in the Omsk and Arkhangelsk regions, water drops contain admixtures of sand and clay, so yellow rain often falls here.

More interesting cases can cause a similar phenomenon. For example, once a yellow rain fell on one of the villages in India, Sangrampur, causing panic among the local population. Fearing the presence of toxic substances in the sediments, analyzes were carried out, the result of which shocked scientists. It turned out that the green, sometimes yellow rain is ordinary bee excrement (several swarms of bees flew by in this area at once), in which traces of honey, pollen of flowers and mango were found.

Green rain can often fall due to impurity chemical substances... For example, a few years ago, it rained green in the Krasnoyarsk Territory. After that, people living in this region began to complain of severe headaches and watery eyes.

Despite the fact that colored rains are an interesting, surprising and impressive phenomenon, it is better not to fall under them: you never know what exactly the water drops were mixed with in each specific case. Well, if nature was the cause of this phenomenon, then colored rain may even be beneficial to health. But if you are unlucky, and you are caught in, for example, white rain or black rain caused by an anthropogenic factor, this will definitely not be reflected in your health in the best way.

The Pambak River in the Lori region in northern Armenia has acquired a reddish hue; water samples were taken for examination.

In April 1999 after the NATO bombing of Yugoslavia and the destruction of petrochemical enterprises, a poisonous "black rain" passed over the town of Pancevo, containing a huge amount of heavy metals and organic compounds harmful to human life. Soil and groundwater have been severely contaminated with ethylene and chlorine. A huge amount of oil, petroleum products, ammonia and amino acids ended up in the Danube.

June-July 2000 in some areas of Dagestan and North Ossetia, in particular, in the city of Vladikavkaz, there were "colored rains". As a result of analyzes of water samples, an increased content of chemical elements was found. They exceeded the maximum permissible concentrations of cobalt (more than four times) and zinc (more than 434 times). Laboratory tests confirmed that the composition of the contaminated rain was identical chemical composition samples taken on the territory of JSC "Electrozinc", which violated the standards of maximum permissible emissions into the atmosphere, approved by the Ministry of Protection environment.

In 2000 and 2002 "rusty" precipitation fell in the Altai Territory and the Altai Republic. The weather anomaly was caused by strong emissions of combustion products at the Ust-Kamenogorsk metallurgical plant.

July-September 2001 "red rains" repeatedly fell in the Indian state of Kerala. Several hypotheses were put forward at once for the origin of red particles: someone considered them red dust carried by the wind from the Arabian desert, someone recognized them as fungal spores or oceanic algae. A version of their extraterrestrial origin was put forward. According to the calculations of scientists, everything fell on the ground along with precipitation in total about 50 tons of this strange substance.

In October 2001 got under abnormal rain residents of the southwestern regions of Sweden. After the rain, gray-yellow stains remained on the surface of the earth. Swedish experts, and in particular a researcher from the Gothenburg Scientific Geocenter Lars Fransen, said that strong winds "sucked in" the red sand dust from the Sahara, raised it to a height of 5 thousand meters and then poured it along with the rain in Sweden.

Summer 2002 green rain poured over the Indian village of Sangranpur near the city of Kolkata. Local authorities announced that there was no chemical attack. An examination of the scientists who arrived at the site determined that the green cloud is nothing more than the pollen of flowers and mangoes contained in bee excrement and does not pose a danger to humans.

In 2003 in Dagestan, precipitation fell in the form of salt deposits. The cars in the open air were covered with a layer of salt. According to meteorologists, the reason for this was a cyclone that came from the regions of Turkey and Iran. The fine particles of sand and dust lifted by a strong wind from the mined quarries in the territory of Dagestan mixed with water dust raised from the surface of the Caspian Sea. The mixture concentrated in the clouds, which moved to the coastal regions of Dagestan, where the unusual rain fell.

In the winter of 2004 orange-colored snow fell in eastern Poland. Then he was observed by residents of Transcarpathia in the villages of Tikhoe and Gusinoe. According to one version, sandstorms in Saudi Arabia: grains of sand, picked up by a strong wind, accumulated in the upper atmosphere and fell out with snow in Transcarpathia.

April 19, 2005 in the Kantemirovsky and Kalacheyevsky districts of the Voronezh region, a red rain fell. Precipitation left an unusual mark on the roofs of houses, fields, agricultural machinery. In a soil sample, traces of ocher, a natural pigment for paint production, were found. It contained iron and clay hydroxides. Further investigation revealed that a release occurred at the ocher plant in the village of Zhuravka, which led to the color of rain clouds in red. According to experts, the fallout was not dangerous for human and animal health.

April 19, 2005 over several districts of the Stavropol Territory, the sky acquired a yellowish tint, and then it began to rain, the drops of which were colorless. After drying, the drops were left on the machines and on dark beige clothes, which were not washed off afterwards. The same rain fell on 22 April in Orel. The analyzes carried out showed that the sediments contained alkali, namely nitrogenous compounds. The precipitation was very concentrated.

In April 2005 for several days orange rains were falling in Ukraine - in the Nikolaev region and in the Crimea. Colored precipitation covered these days also Donetsk, Dnepropetrovsk, Zaporozhye, Kherson regions. Ukrainian forecasters said that the rain acquired orange color as a result of a dust hurricane. The wind brought dust particles from North Africa.

In February 2006 gray-yellow snow fell on the territory of the village of Sabo, located 80 km south of the city of Okha in the north of Sakhalin. According to eyewitnesses, oily spots of gray-yellow color and with an unusual strange odor were formed on the surface of the water obtained by melting suspicious snow. Experts believe that unusual precipitation could be the consequences of the activity of one of the Far Eastern volcanoes. It is possible that the pollution of the environment with products of the oil and gas industry is to blame. The reason for the yellowing of the snow has not been precisely determined.

February 24-26, 2006 in some areas of Colorado (USA) it was snowing brown, almost like chocolate in color. "Chocolate" snow in Colorado is a consequence of a prolonged drought in neighboring Arizona: there are giant clouds of dust mixed with snow. Sometimes volcanic eruptions give the same result.

In March 2006 in the north of Primorsky Territory, creamy pink snow fell. Experts explained the unusual phenomenon by the fact that the cyclone had previously passed through the territory of Mongolia, where at that time strong dust storms raged, covering large areas of desert territories. Dust particles were entrained in the cyclone vortex and colored the sediments.

March 13, 2006 in South Koreaincluding Seoul, yellow snow fell. The snow was yellow due to the content of yellow sand brought in from the deserts of China. Meteorological service the country warned that fine sandy snow could be hazardous to the respiratory system.

November 7, 2006 in Krasnoyarsk fine snow fell with rain of green color. He walked for about half an hour and, having melted, turned into a thin layer of greenish clay. People exposed to green rain experienced watery eyes and headaches.

January 31, 2007 in the Omsk region, on an area of \u200b\u200babout 1.5 thousand square kilometers, yellow-orange snow with a pungent smell, covered with oily spots, fell. Having passed through the entire Irtysh region, a plume of yellow-orange precipitation caught the Tomsk region along the edge. But the bulk of the "acidic" snow fell in the Tarsky, Kolosovsky, Znamensky, Sedelnikovsky and Tyukalinsky districts of the Omsk region. In colored snow, the iron content norm was exceeded (according to preliminary laboratory data, the iron concentration in the snow was 1.2 mg per cubic centimeter at the maximum permissible rate in 0.3 mg). According to Rospotrebnadzor, such a concentration of iron is not dangerous to human life and health. Laboratories in Omsk, Tomsk and Novosibirsk were engaged in the study of anomalous precipitation. Initially, it was assumed that the snow contains the poisonous substance heptyl, which is a component of rocket fuel. The second version of the appearance of yellow precipitation was emissions from metallurgical enterprises in the Urals. However, the Tomsk and Novosibirsk experts came to the same conclusion as the Omsk ones - the unusual color of the snow is due to the presence of clay-sand dust, which could have got into the Omsk region from Kazakhstan. No toxic substances were found in the snow.

In March 2008 yellow snow fell in the Arkhangelsk region. Experts have suggested that the yellow color of the snow is due to natural factors. This is caused by the high content of sand that got into the clouds as a result of dust storms and tornadoes that occurred elsewhere on the planet.

Lesson objectives:

determination of the factors causing the color of chemicals;
expansion and systematization of knowledge on the chemical foundations of the theory of color origin;
development cognitive interest to the study of qualitative reactions.

Formed competencies of students:

the ability to analyze the phenomena of the surrounding world in chemical terms;
the ability to explain the chemical phenomena associated with the appearance of the color of solutions;
willingness to independently work with information;
willingness to interact with colleagues and speak to an audience.

"All living things strive for color."W. Goethe

Knowledge update

In the previous sessions, we studied the properties of inorganic and organic substances, often using qualitative reactions that indicate the presence of a particular substance by color, smell or sediment. The proposed crossword puzzle consists of the names of chemical elements that have color differences

Crossword solution:

Vertically:

1) A substance that turns the flame purple (potassium).

2) The lightest silver-colored metal (lithium).

Horizontally:

3) The name of this element is "green line" (thallium)

4) Metal that paints the glass blue (niobium)

5) The name of the metal means sky blue (cesium)

6) Courtois first received purple vapors of this substance thanks to his cat (iodine).

Motivation learning activities.

Please note that the solution to the crossword puzzle was related to the color of the substances. But not only chemicals, but the world around us is colorful.

"All living things strive for color." These words of the great genius of poetry correctly reflect the peculiarity of the emotions that a particular color evokes in us. We perceive it associatively, i.e. we recall something familiar and familiar. The perception of color is accompanied by certain emotions. (Demonstration of paintings by artists).

Students answer color perception questions about emotions.

Blue evokes calmness, it is pleasant, and increases the assessment of self-affirmation.
Green is the color of green plants, the mood of peace, tranquility.
Yellow - the spirit of happiness, fun, associated with the sun.
Red is the color of activity, action, you want to achieve results.
Black - causes sadness, irritation.

Why then the world colorful?

Today we are trying to find an answer to the question "What is color?" in terms of chemistry.

The topic of the lesson is "Color chemistry of qualitative reactions".

Determination of color factors

It is impossible to consider the chemical essence of color without knowledge of the physical properties of visible light. Without light, there is no coloring of objects, everything seems dark. Light is electromagnetic waves. How much joy a rainbow in the sky brings to both children and adults, however, it appears only if the sun's rays are reflected in water droplets and return to the human eye with a multi-colored spectrum. We are indebted to the great English physicist Isaac Newton for explaining this phenomenon: white is a collection of rays of different colors. Each wavelength corresponds to a certain energy that these waves carry. The color of any substance is determined by the wavelength, the energy of which prevails in the given radiation. The color of the sky depends on how much of the sunlight reaches our eyes. Short wavelength beams (blue) are reflected from air molecules and scattered. Our eye perceives them and determines the color of the sky - blue, blue (Table 1.)

Table 1 - The color of substances with one absorption band in the visible part of the spectrum.

The same is true for colored substances. If a substance reflects rays of a certain wavelength, then it is colored. If the energy of light waves of the entire spectrum is equally absorbed or reflected, then the substance appears black or white. You know from biology lessons that the human eye contains an optical system: the lens and the vitreous humor. The retina includes light-sensitive elements: cones and rods. Thanks to the cones, we distinguish colors.

Thus, what we call color is the result of two physicochemical phenomena: the interaction of light with molecules of a substance and the effect of waves coming from the substance on the retina of the eyes.

1 factor of color formation is light.

Let's consider examples of the following factor - the structure of substances.

Metals have a crystalline structure, they have an ordered structure of atoms and electrons. Color is related to the mobility of electrons. When illuminating metals, reflection predominates, their color depends on the wavelength that they reflect. (Demonstration of the collection of metals). The white sheen is due to the uniform reflection of almost the entire set of visible rays. This is the color of aluminum and zinc. Gold is reddish yellow in color because it absorbs light blue, blue and violet rays. Copper also has a reddish color. Magnesium powder is black, which means this substance absorbs the entire spectrum of rays.

Let's see how the color of a substance changes from the state of the structure using the example of sulfur.

Demonstration of the video film "Chemical Elements".

We conclude: sulfur in the crystalline state is yellow, and in the amorphous state it is black, i.e. in this case, the color factor is the structure of the substance.

What happens to the color of substances when the structure is destroyed, for example, during the dissociation of salt molecules, if these solutions are colored.

CuS0 4 (blue) Cu 2+ + SO 4 2-

NiS0 4 (green) Ni 2+ + SO 4 2-

CuCI 2 (blue) Cu 2+ + 2CI -

FeCI 3 (yellow) Fe 3+ + 3CI -

In these solutions, the anions are the same; different cations give the color.

The following solutions have the same cation, but different anions, which means that the anions are responsible for the color:

K 2 Cr 2 O 7 (orange) 2K + + Cz 2 O 4 2-

K 2 Cr0 4 (yellow) 2K + + Cz0 4 2-

KMnO 4 (purple) K + + Mn04 -

The third factor in the appearance of color is the ionic state of substances.

The color also depends on the environment around the colored particles. Cations and anions in solution are surrounded by a shell of a solvent that affects the ions.

We conduct the following experiment. There is a solution of beet juice (raspberry color). Add the following substances to this solution:

experience. Beet juice solution and acetic acid
experience. Beet juice solution and NH 4 0H solution
experience. Beet juice solution and water.

In 1 experiment, an acidic environment leads to a color change to purple, in 2 experiments, an alkaline medium changes the color of beets to blue, and the addition of water (neutral medium) does not cause color changes.

Known indicator for the determination of an alkaline medium - phenolphthalein, which changes the color of alkali solutions to raspberry.

Experiment is carried out:

NaOH + phenolphthalein -\u003e raspberry color

We conclude: the 4th factor of color change is the environment.

Consider the case of surrounding an atom of one element with different complexes.

An experiment is being carried out: a qualitative reaction to the Fe 3+ ion:

FeCl 3 + KCNS -\u003e red

FeCl 3 + K 4 (Fe (CN) 6) -\u003e p-p dark blue

A historical fact is associated with the change in the color of the iron ion when it is surrounded by potassium thiocyanate into a bloody color.

Help from students.

In 1720, the political opponents of Peter I from the clergy organized a "miracle" in one of the St. Petersburg cathedrals - the icon of the Mother of God began to shed tears, which was commented on as a sign of her disapproval of Peter's reforms. Peter I carefully examined the icon and noticed something suspicious: he found small holes in the eyes of the icon. He also found the source of tears: it was a sponge soaked in a solution of iron rhodanip, which has a blood-red color. The weight evenly pressed on the sponge, squeezing the drops through the hole in the icon. "This is the source of wonderful tears," said the emperor.

Experimenting.

On paper, write the words with solutions CuS0 4 (blue) and FeСI 3 (yellow), then treat the leaf with yellow blood salt K 4 (Fe (CN) 6). The word CuSO 4 (blue) turns red and the word FeCI 3 (yellow) turns blue-green. There is no change in the oxidation state of the metal, only the environment changed:

2CuS0 4 + K 4 (Fe (CN) 6) Cu 2 (Fe (CN) 6) + 2K 2 SO 4

4FeCl 3 + 3 K 4 (Fe (CN) 6) Fe 4 (Fe (CN) 6) 3 +12 KCI

5 color factor - the surrounding of ions with complexes.

Conclusion.

We have identified the main factors influencing the color development of substances.

We realized that color is the result of absorption of a certain part of the visible spectrum of sunlight by a substance.

A qualitative reaction is a special reaction that detects ions or molecules by color.

Messages from students on the topic "Color serves people."

The blood of animals and green leaves contain similar structures, but the blood contains iron ions - Fe, and plants - Mg. This provides the color: red and green. By the way, the saying "blue blood" is true for deep-sea animals, which have vanadium in their blood instead of iron. Likewise, algae growing in places where there is little oxygen are blue in color.

Plants with chlorophyll are able to form organomagnesium substances and use the energy of light. The color of photosynthetic plants is green.

Blood hemoglobin, which contains iron, is used to transport oxygen in the body. Hemoglobin with oxygen makes the blood bright red, and without oxygen it makes the blood dark.

Paints and dyes are used by painters, decorators and textile workers. Harmony of color is an integral part of the art of "design". The oldest paints were charcoal, chalk, clay, cinnabar, and some salts such as copper acetate (copperhead).

Luminous paints are used for road signs and advertisements, lifeboats.

For the purpose of bleaching, substances are added to the composition of washing powders that give the fabric a bluish fluorescence.

The surface of all metal objects is destroyed by the environment. Their protection is most effective with colored pigments: aluminum powder, zinc dust, red lead, chromium oxide.

Reflection.

1. What factors cause the color of chemicals?

2. What substances can be determined by qualitative color change reactions?

3. What factors determine the color of potassium and copper salts?

Nature, of which chemicals are a part, surrounds us with mysteries, and trying to solve them is one of the greatest joys in life.

Today we have tried to approach the truth "Chemistry of Color" from one side, and maybe the other will be revealed to you. The most important thing is that the world of color is cognizable.

Man is born into the world
To create, dare - and not otherwise,
To leave a good mark in life,
And solve all the difficult tasks.
For what? Look for your answer!

Homework.

Give examples of qualitative reactions to iron ions by color change.

The Pambak River in the Lori region in northern Armenia has acquired a reddish hue; water samples were taken for examination.

June-July 2000 in some areas of Dagestan and North Ossetia, in particular, in the city of Vladikavkaz, there were "colored rains". As a result of analyzes of water samples, an increased content of chemical elements was found. They exceeded the maximum permissible concentrations of cobalt (more than four times) and zinc (more than 434 times). Laboratory studies confirmed that the composition of the polluted rain was identical to the chemical composition of samples taken at the territory of Electrozinc, which violated the standards for maximum permissible emissions into the atmosphere approved by the Ministry of Environmental Protection.

July-September 2001 "red rains" have repeatedly fallen in the Indian state of Kerala. Several hypotheses were put forward at once for the origin of red particles: someone considered them red dust carried by the wind from the Arabian desert, someone recognized them as fungal spores or oceanic algae. A version of their extraterrestrial origin was put forward. According to scientists' calculations, a total of about 50 tons of this strange substance fell on the ground along with precipitation.

In October 2001 residents of the southwestern regions of Sweden were caught in abnormal rain. After the rain, gray-yellow stains remained on the surface of the earth. Swedish experts, and in particular a researcher from the Gothenburg Scientific Geocenter Lars Fransen, said that strong winds "sucked in" the red sand dust from the Sahara, raised it to a height of 5 thousand meters and then poured it along with the rain in Sweden.

In the winter of 2004 orange-colored snow fell in eastern Poland. Then he was observed by the inhabitants of Transcarpathia in the villages of Tikhoe and Gusinoe. According to one of the versions, sandstorms in Saudi Arabia caused the orange color of the snow: grains of sand caught by a strong wind accumulated in the upper atmosphere and fell out with the snow in Transcarpathia.

March 13, 2006 yellow snow fell in South Korea, including Seoul. The snow was yellow due to the content of yellow sand brought in from the deserts of China. The country's meteorological service has warned that snow with fine sand can be dangerous to the respiratory system.

January 31, 2007 in the Omsk region, on an area of \u200b\u200babout 1.5 thousand square kilometers, yellow-orange snow with a pungent smell, covered with oily spots, fell. Having passed through the entire Irtysh region, a plume of yellow-orange precipitation caught the Tomsk region along the edge. But the bulk of the "acidic" snow fell in the Tarsky, Kolosovsky, Znamensky, Sedelnikovsky and Tyukalinsky districts of the Omsk region. In colored snow, the iron content rate was exceeded (according to preliminary laboratory data, the iron concentration in the snow was 1.2 mg per cubic centimeter with the maximum allowable rate of 0.3 mg). According to Rospotrebnadzor, such a concentration of iron is not dangerous to human life and health. Laboratories in Omsk, Tomsk and Novosibirsk were engaged in the study of anomalous precipitation. Initially, it was assumed that the snow contains the poisonous substance heptyl, which is a component of rocket fuel. The second version of the appearance of yellow precipitation was emissions from metallurgical enterprises in the Urals. However, the Tomsk and Novosibirsk experts came to the same conclusion as the Omsk ones - the unusual color of the snow is due to the presence of clay-sand dust, which could have got into the Omsk region from Kazakhstan. No toxic substances were found in the snow.

Chemical precipitation and their color table. Color chemistry of qualitative reactions. Motivation for learning activities

Rain with a red tint

Black rain

Snow white rain

Yellow and green precipitation

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